The effect of solvent dynamics on the low frequency collective motions of DNA in solution and unoriented films.
نویسندگان
چکیده
Infrared spectroscopy is used to probe the dynamics of in vitro samples of DNA prepared as solutions and as solid unoriented films. The lowest frequency DNA mode identified in the far-infrared spectra of the DNA samples is found to shift in frequency when the solvent influence in the hydration shell is altered. The lowest frequency mode also has characteristics that are similar to beta-relaxations identified in other glass forming polymers.
منابع مشابه
Study of Photo-Conductivity in MoS2 Thin Films Grown in Low-Temperature Aqueous Solution Bath
An experimental study over the optical response of thin MoS2 films grownby chemical bath deposition (CBD) method is presented. As two important factors, theeffect of bath temperature and growth time are considered on the photocurrentgeneration in the grown samples. The results show that increasing the growth time leadsto better optical response and higher difference betw...
متن کاملInvestigation of Solvent Effect on CUA Codon Mutation: NMR Shielding Study
P53 is one of the gene that has important role in human cell cycle and in the human cancers too.Models of codon substitution make it possible to separate mutational biases in the DNA fromselective constraints on the protein, and offer a great advantage over amino acid models forunderstanding the evolutionary process of proteins and protein-coding DNA sequences. In thiswork, we investigated abou...
متن کاملEffect of Follower Force on Vibration Frequency of Magneto-Strictive-Faced Sandwich Plate with CNTR Composite Core
This study deals with the vibration response of sandwich plate with nano-composite core and smart magneto-strictive face sheets. Composite core is reinforced by carbon nanotubes (CNTs) and its effective elastic properties are obtained by the rule of Mixture. Terfenol-D films are used as the face sheets of sandwich due to magneto-mechanical coupling in magneto-strictive material (MsM). In order ...
متن کاملAPPLICATION OF THE SINGULAR BOUNDARY VALUE PROBLEM FOR INVESTIGATION OF PISTON DYNAMICS UNDER POLYTROPIC EXPANSION PROCESS
In this paper a mathematical simulation of a simplified internal combustion engine is presented. To contribute engine kinematics and its geometry, simple relations are derived for constrained motions. The equation of motion for the piston forms a singular boundary value problem. The uniqueness of the solution was studied in the Banach space. For solving governing equations an iterative numerica...
متن کاملMolecular dynamics studies on the denaturation of polyalanine in the presence of guanidinium chloride at low concentration
Molecular dynamic simulation is a powerful method that monitors all variations in the atomic level in explicit solvent. By this method we can calculate many chemical and biochemical properties of large scale biological systems. In this work all-atom molecular dynamics simulation of polyalanine (PA) was investigated in the presence of 0.224, 0.448, 0.673, 0.897 and 1.122 M of guanidinium chlorid...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- The Journal of chemical physics
دوره 124 22 شماره
صفحات -
تاریخ انتشار 2006